[Au14(PPh3)8(NO3)4]: An Example of a New Class of Au(NO3)-Ligated Superatom Complexes

被引：73

作者：

Gutrath, Benjamin S. ^{[1
,2
]}

Oppel, Iris M. ^{[1
,2
]}

Presly, Oliver ^{[3
]}

Beljakov, Igor ^{[4
]}

Meded, Velimir ^{[4
]}

Wenzel, Wolfgang ^{[4
]}

Simon, Ulrich ^{[1
,2
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany

[2] JARA Fundamentals Future Informat Technol, D-52074 Aachen, Germany

[3] Agilent Technol UK Ltd, Yarnton OX5 1QU, Oxon, England

[4] Karlsruhe Inst Technol, Inst Nanotechnol, D-76021 Karlsruhe, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 12期

关键词：

cluster compounds; gold; nanotechnology; quantum dots; structure elucidation; RAY STRUCTURE DETERMINATION; GOLD CLUSTERS; STRUCTURAL-CHARACTERIZATION; ELECTRONIC-STRUCTURE; NANOPARTICLES; COLLOIDS; CRYSTAL; LIGANDS;

D O I：

10.1002/anie.201208681

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Golden beauty: For the first time a ligand-stabilized Au14 cluster has been examined. The structure of this superatom complex bears several impressive and unique features, which will further support the understanding of certain guiding principles for molecular-precision synthesis and functionalization of ultrasmall nanoparticles. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3529 / 3532

页数：4

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