Ruthenium-Based Electrocatalysts Supported on Reduced Graphene Oxide for Lithium-Air Batteries

被引：358

作者：

Jung, Hun-Gi ^{[1
]}

Jeong, Yo Sub ^{[1
]}

Park, Jin-Bum ^{[1
]}

Sun, Yang-Kook ^{[1
]}

Scrosati, Bruno ^{[1
,2
]}

Lee, Yun Jung ^{[1
]}

机构：

[1] Hanyang Univ, Dept Energy Engn, Seoul 133791, South Korea

[2] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy

来源：

ACS NANO | 2013年 / 7卷 / 04期

基金：

新加坡国家研究基金会;

关键词：

reduced graphene oxide; supported catalysts; ruthenium oxide; lithium-air battery; organic electrolyte; OXYGEN EVOLUTION; HYDROTHERMAL SYNTHESIS; WATER; OXIDATION; CATALYSTS; RUO2; NANOPARTICLES; ELECTROLYSIS; NANOSHEETS; CATHODE;

D O I：

10.1021/nn400477d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium-based nanomaterials supported on reduced graphene oxide (rGO) have been investigated as air cathodes in non-aqueous electrolyte Li-air cells using a TEGDME-LiCF3SO3 electrolyte. Homogeneously distributed metallic ruthenium and hydrated ruthenium oxide (RuO2 center dot 0.64H(2)O), deposited exclusively on rGO, have been synthesized with average size below 2.5 nm. The synthesized hybrid materials of Ru-based nanoparticles supported on rGO efficiently functioned as electrocatalysts for Li2O2 oxidation reactions, maintaining cycling stability for 30 cycles without sign of TEGDME-LiCF3SO3 electrolyte decomposition. Specifically, RuO2 center dot 0.64H(2)O-rGO hybrids were superior to Ru-rGO hybrids in catalyzing the OER reaction, significantly reducing the average charge potential to similar to 3.7 Vat the high current density of 500 mA g(-1) and high specific capacity of 5000 mAh g(-1).

引用

页码：3532 / 3539

页数：8

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