A Metal-Directed Self-Assembled Electroactive Cage with Bis(pyrrolo)tetrathiafulvalene (BPTTF) Side Walls

被引：90

作者：

Bivaud, Sebastien ^{[1
]}

Balandier, Jean-Yves ^{[1
]}

Chas, Marcos ^{[1
]}

Allain, Magali ^{[1
]}

Goeb, Sebastien ^{[1
]}

Salle, Marc ^{[1
]}

机构：

[1] Univ Angers, LUNAM Univ, CNRS, Lab MOLTECH Anjou,UMR 6200, F-49045 Angers, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 29期

关键词：

MOLECULAR FLASKS; BUILDING-BLOCKS; COORDINATION; CHEMISTRY; TETRATHIAFULVALENES; METALLACYCLES; DERIVATIVES; DISCRETE; ANIONS;

D O I：

10.1021/ja305451v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A straightforward synthesis of a bis-(pyrrolo)tetrathiafulvalene (BPTTF)-based tetratopic ligand bearing four pyridyl units is described The first example of a TTF-based self assembled cage has been produced from this redox-active ligand through metal directed synthesis with a cis-coordinated square-planar Pt(II) complex. The resulting cage corresponds to a trigonal-prismatic structure, as shown by X-ray crystallography. A UV-vis titration indicated that the electron-rich cavity can be used to incorporate one molecule of tetrafluorotetracyano-p-quinodimethane (TCNQF(4)).

引用

页码：11968 / 11970

页数：3

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