Desulfurization and transformation of isothiocyanates to cyanamides by using sodium bis(trimethylsilyl)amide

被引:37
作者
Chen, Chun-Yen [2 ]
Wong, Fung Fuh [1 ]
Huang, Jiann-Jyh [3 ]
Lin, Shao-Kai [4 ]
Yeh, Mou-Yung [2 ]
机构
[1] China Med Univ, Grad Inst Pharmaceut Chem, Taichung 40402, Taiwan
[2] Natl Cheng Kung Univ, Dept Chem, Tainan 70101, Taiwan
[3] Dev Ctr Biotechnol, Xizhi City, Taipei County, Taiwan
[4] Natl Cheng Kung Univ, Sustainable Environm Res Ctr, Tainan 709, Taiwan
关键词
Cyanamides; Isothiocyanates; Sodium bis(trimethylsilyl)amide; Desulfurization;
D O I
10.1016/j.tetlet.2008.08.106
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Sodium bis(trimethylsilyl)amide was first used as the desulfurizing agent for the conversion of isothiocyanates to cyanamides in a 'one-flask' reaction. Crown Copyright (C) 2008 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:6505 / 6507
页数:3
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