Halogen bonding-based anion coordination in calixarene/inorganic halide/diiodoperfluorocarbon assemblies

被引：22

作者：

Biella, Serena ^{[1
]}

Gattuso, Giuseppe ^{[2
]}

Notti, Anna ^{[2
]}

Metrangolo, Pierangelo ^{[1
]}

Pappalardo, Sebastiano ^{[3
]}

Parisi, Melchiorre F. ^{[2
]}

Pilati, Tullio ^{[4
]}

Resnati, Giuseppe ^{[1
]}

Terraneo, Giancarlo ^{[1
]}

机构：

[1] Politecn Milan, NFM Lab DIMIC G Natta, I-20133 Milan, Italy

[2] Univ Messina, Dipartimento Chim Organ & Biol, Messina, Italy

[3] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy

[4] Univ Milan, CNR, ISTM, Milan, Italy

来源：

SUPRAMOLECULAR CHEMISTRY | 2009年 / 21卷 / 1-2期

关键词：

anion coordination; calixarenes; comb-like copolymer; halogen bonding; X-ray; CHEMICALLY-MODIFIED CALIXARENES; SUPRAMOLECULAR CHEMISTRY; CATION COMPLEXATION; MOLECULAR RECOGNITION; EXPANDED PORPHYRINS; CARBON TETRABROMIDE; PHYSICAL-PROPERTIES; ALKALI CATIONS; CROWN-ETHERS; RECEPTORS;

D O I：

10.1080/10610270802516955

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly of ternary mixtures composed of cation segregating agent/inorganic halide (penta-tert-butyl-pentakis(ethoxycarbonylmethoxy)calix[5]arene (1)/NaI or 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8,8,8]hexacosane (4)/BaI2) and diiodoperfluorocarbon (1,8-diiodoperfluorooctane (2)) produces crystalline supramolecular salts 3 and 5, respectively, whose structural characteristics in the solid state have been elucidated by single-crystal X-ray analyses. Encapsulation of alkali or alkaline-earth metal ions inside the complexing pocket of the appropriate receptor generates naked iodide anions, which effectively drive the self-assembly of diiodoperfluorooctane 2 into halogen-bonded supramolecular anions with a comb-like copolymer structure. [image omitted].

引用

页码：149 / 156

页数：8

共 79 条

[1] Synthesis and reactivity of Ru-, Os-, Rh-, and Ir-halide-sulfoxide complexes [J].

Alessio, E .

CHEMICAL REVIEWS, 2004, 104 (09) :4203-4242

[2] Hybrid iodoperfluoroalkane-ferrocene supramolecular arrays: the shortest contacts iodine forms with nitrogen atoms and unsaturated moieties [J].

Amati, M ;

Lelj, F ;

Liantonio, R ;

Metrangolo, P ;

Luzzati, S ;

Pilati, T ;

Resnati, G .

JOURNAL OF FLUORINE CHEMISTRY, 2004, 125 (04) :629-640

[3] What anions do to N-H-containing receptors [J].

Amendola, Valeria ;

Esteban-Gomez, David ;

Fabbrizzi, Luigi ;

Licchelli, Maurizio .

ACCOUNTS OF CHEMICAL RESEARCH, 2006, 39 (05) :343-353

[4] N-confused calix[4]pyrroles [J].

Anzenbacher, Pavel, Jr. ;

Nishiyabu, Ryuhei ;

Palacios, Manuel A. .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (23-24) :2929-2938

[5] CATION COMPLEXATION BY CHEMICALLY-MODIFIED CALIXARENES .7. TRANSPORT OF ALKALI CATIONS BY P-TERT-BUTYLCALIX[N]ARENE ESTERS AND AMIDES [J].

ARNAUDNEU, F ;

FANNI, S ;

GUERRA, L ;

MCGREGOR, W ;

ZIAT, K ;

SCHWINGWEILL, MJ ;

BARRETT, G ;

MCKERVEY, MA ;

MARRS, D ;

SEWARD, EM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (01) :113-118

[6] Metal sulfonatocalix[4,5]arene complexes: bi-layers, capsules, spheres, tubular arrays and beyond [J].

Atwood, JL ;

Barbour, LJ ;

Hardie, MJ ;

Raston, CL .

COORDINATION CHEMISTRY REVIEWS, 2001, 222 :3-32

[7] Chiral salen complexes: An overview to recoverable and reusable homogeneous and heterogeneous catalysts [J].

Baleizao, Carlos ;

Garcia, Hermenegildo .

CHEMICAL REVIEWS, 2006, 106 (09) :3987-4043

[8] CATION COMPLEXATION BY CHEMICALLY-MODIFIED CALIXARENES .6. ALKALI AND SILVER(I) CATION COMPLEXATION BY P-TERT-BUTYLCALIX[5]ARENE DERIVATIVES AND X-RAY STRUCTURE DETERMINATION OF A PENTAESTER [J].

BARRETT, G ;

MCKERVEY, MA ;

MALONE, JF ;

WALKER, A ;

ARNAUDNEU, F ;

GUERRA, L ;

SCHWINGWEILL, MJ ;

GUTSCHE, CD ;

STEWART, DR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (08) :1475-1479

[9] Cation complexation by chemically modified calixarenes.: 11.: Complexation and extraction of alkali cations by calix[5]- and -[6]arene ketones.: Crystal and molecular structures of calix[5]arene ketones and Na+ and Rb+ complexes [J].

Bell, SEJ ;

Browne, JK ;

McKee, V ;

McKervey, MA ;

Malone, JF ;

O'Leary, M ;

Walker, A ;

Arnaud-Neu, F ;

Boulangeot, O ;

Mauprivez, O ;

Schwing-Weill, MJ .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (03) :489-501

[10]

Bertani R, 2002, ADV MATER, V14, P1197, DOI 10.1002/1521-4095(20020903)14:17<1197::AID-ADMA1197>3.0.CO

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