Resonance Raman evidence for the interconversion between an [FeIII-η1-OOH] 2+ and [FeIII-η2-O2]+ species and mechanistic implications thereof

被引：82

作者：

Ho, RYN

Roelfes, G

Hermant, R

Hage, R

Feringa, BL ^{[1
]}

Que, L

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA

[3] Univ Groningen, Dept Organ & Mol Inorgan Chem, NL-9747 AG Groningen, Netherlands

[4] Unilever Res Labs Vlaardingen, NL-3133 AT Vlaardingen, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 21期

关键词：

D O I：

10.1039/a905535e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The deprotonation of [Fe-III(N4Py)(eta(1)-OOH)](2+) 1 gives [Fe-III(N4Py)(eta(2)-OO)](+) 2, as unequivocally demonstrated by resonance Raman spectroscopy, and leads to the loss of alkane hydroxylation activity by 1.

引用

页码：2161 / 2162

页数：2

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