Facile reduction of poly (2,5-dialkoxy-p-phenylene ethynylene)s:: An efficient route for the synthesis of poly (2,5-dialkoxy-p-xylylene)s

被引:23
作者
Beck, JB [1 ]
Kokil, A [1 ]
Ray, D [1 ]
Rowan, SJ [1 ]
Weder, C [1 ]
机构
[1] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA
关键词
D O I
10.1021/ma011386g
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A study was carried out to show that diimide generated from p-toluenesulfonhydrazide and tripropylamine is a convenient and very effective reagent for the hydrogenation of PPEs under mild and undemanding conditions. In the initial experiments, this protocol was employed to reduce two different PPE derivatives to the corresponding poly(p-xylene)s.
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收藏
页码:590 / 593
页数:4
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