Electroactive multifunctional telechelic stairs-shaped poly(bicarbazyl-alkylene)s

被引：16

作者：

Cloutet, E ^{[1
]}

Yammine, P ^{[1
]}

Adés, D ^{[1
]}

Siove, A ^{[1
]}

机构：

[1] Univ Paris 13, Inst Galilee, CNRS, Lab Rech Macromol, F-93430 Villetaneuse, France

来源：

SYNTHETIC METALS | 1999年 / 102卷 / 1-3期

关键词：

polycarbazoles; chemical synthesis; electrochemical doping; electroluminescence;

D O I：

10.1016/S0379-6779(98)00983-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Chemical oxidation of alpha,omega-bis(N-carbazolyl)alkanes by FeCl3 in the presence of N-(omega-functional alkyl)carbazoles allowed the obtention of telechelic stairs-shaped poly(bicarbazyl-alkylene)s bearing terminal groups such as halogens, nitrile, carboxylic acid. High molar masses materials were obtained exhibiting a particularly good solubility in organic solvents due to their special architecture. Electrochemical studies disclosed that redox polymers were obtained displaying a remarkable colourless<->green<->blue electrochromism. Furthermore materials could be used as a blue light-emitting layer into diodes.

引用

页码：1302 / 1303

页数：2

共 7 条

[1] SYNTHESIS AND CHARACTERIZATION OF POLY(N-BUTYL-3,6-CARBAZOLEDIYL) - A NEW SOLUBLE ELECTROACTIVE MATERIAL [J].