A novel terthienyl based polymer electrochrome with peripheral BODIPY

被引：15

作者：

Algi, Fatih ^{[1
]}

Cihaner, Atilla ^{[2
]}

机构：

[1] Canakkale Onsekiz Mart Univ, LOM, TR-17100 Canakkale, Turkey

[2] Atilim Univ, Atilim Optoelect Mat & Solar Energy Lab ATOMSEL, TR-06836 Ankara, Turkey

来源：

POLYMER | 2012年 / 53卷 / 16期

关键词：

Bodipy; Terthienyl; Electrochromic; RESONANCE ENERGY-TRANSFER; CONDUCTING POLYMERS; FLUORESCENT-PROBE; SOLAR-CELLS; EMISSION; RED; DYES; CHEMOSENSOR; MODULATION; CHEMISTRY;

D O I：

10.1016/j.polymer.2012.06.007

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Design, synthesis and electropolymerization of a new hybrid material based on terthienyl system bearing BODIPY appendage are reported. This electrochemically polymerized unique combination readily gives an electrochromic polymer with a narrow optical band gap (1.71 eV). The electrochrome exhibits purple color when neutralized and sky blue color when oxidized in a monomer-free electrolyte solution containing 0.1 M tetrabutylammonium tetrafluoroborate dissolved in acetonitrile. Spectroscopic and electrochemical features of the electroactive polymer electrochrome indicate that it is a promising candidate for electrochromic device and display applications. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：3469 / 3475

页数：7

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