A novel terthienyl based polymer electrochrome with peripheral BODIPY

被引：15

作者：

Algi, Fatih ^{[1
]}

Cihaner, Atilla ^{[2
]}

机构：

[1] Canakkale Onsekiz Mart Univ, LOM, TR-17100 Canakkale, Turkey

[2] Atilim Univ, Atilim Optoelect Mat & Solar Energy Lab ATOMSEL, TR-06836 Ankara, Turkey

来源：

POLYMER | 2012年 / 53卷 / 16期

关键词：

Bodipy; Terthienyl; Electrochromic; RESONANCE ENERGY-TRANSFER; CONDUCTING POLYMERS; FLUORESCENT-PROBE; SOLAR-CELLS; EMISSION; RED; DYES; CHEMOSENSOR; MODULATION; CHEMISTRY;

D O I：

10.1016/j.polymer.2012.06.007

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Design, synthesis and electropolymerization of a new hybrid material based on terthienyl system bearing BODIPY appendage are reported. This electrochemically polymerized unique combination readily gives an electrochromic polymer with a narrow optical band gap (1.71 eV). The electrochrome exhibits purple color when neutralized and sky blue color when oxidized in a monomer-free electrolyte solution containing 0.1 M tetrabutylammonium tetrafluoroborate dissolved in acetonitrile. Spectroscopic and electrochemical features of the electroactive polymer electrochrome indicate that it is a promising candidate for electrochromic device and display applications. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：3469 / 3475

页数：7

共 64 条

[51]

Rosseinsky DR, 2001, ADV MATER, V13, P783, DOI 10.1002/1521-4095(200106)13:11<783::AID-ADMA783>3.0.CO

[52]

2-D

[53] A tailored hybrid BODIPY-oligothiophene donor for molecular bulk heterojunction solar cells with improved performances [J].

Rousseau, Theodulf ;

Cravino, Antonio ;

Ripaud, Emilie ;

Leriche, Philippe ;

Rihn, Sandra ;

De Nicola, Antoinette ;

Ziessel, Raymond ;

Roncali, Jean .

CHEMICAL COMMUNICATIONS, 2010, 46 (28) :5082-5084

[54] Fluorescent Labeling of Biomolecules with Organic Probes [J].

Sameiro, M. ;

Goncalves, T. .

CHEMICAL REVIEWS, 2009, 109 (01) :190-212

[55] Self-organized discotic liquid crystals for high-efficiency organic photovoltaics [J].

Schmidt-Mende, L ;

Fechtenkötter, A ;

Müllen, K ;

Moons, E ;

Friend, RH ;

MacKenzie, JD .

SCIENCE, 2001, 293 (5532) :1119-1122

[56] Electrochromic conducting polymers via electrochemical polymerization of bis(2-(3,4-ethylenedioxy)thienyl) monomers [J].

Sotzing, GA ;

Reynolds, JR ;

Steel, PJ .

CHEMISTRY OF MATERIALS, 1996, 8 (04) :882-889

[57] Design of a Highly Sensitive Fluorescent Probe for Interfacial Electron Transfer on a TiO2 Surface [J].

Tachikawa, Takashi ;

Wang, Nan ;

Yamashita, Soichiro ;

Cui, Shi-Cong ;

Majima, Tetsuro .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (46) :8593-8597

[58] Brilliant BODIPY-Fluorene Copolymers with Dispersed Absorption and Emission Maxima [J].

Thivierge, Cliferson ;

Loudet, Aurore ;

Burgess, Kevin .

MACROMOLECULES, 2011, 44 (10) :4012-4015

[59] The chemistry of fluorescent bodipy dyes: Versatility unsurpassed [J].

Ulrich, Gilles ;

Ziessel, Raymond ;

Harriman, Anthony .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (07) :1184-1201

[60] Advances in the chemistry of dipyrrins and their complexes [J].

Wood, Tabitha E. ;

Thompson, Alison .

CHEMICAL REVIEWS, 2007, 107 (05) :1831-1861

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