Synthesis of single crystalline hexagonal nanobricks of LiNi1/3Co1/3Mn1/3O2 with high percentage of exposed {010} active facets as high rate performance cathode material for lithium-ion battery

被引:218
作者
Fu, Fang [1 ]
Xu, Gui-Liang [1 ]
Wang, Qi [1 ]
Deng, Ya-Ping [1 ]
Li, Xue [1 ]
Li, Jun-Tao [1 ]
Huang, Ling [1 ]
Sun, Shi-Gang [1 ]
机构
[1] Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Sch Energy Res,Dept Chem, Xiamen 361005, Peoples R China
关键词
HIGH-ENERGY CATHODE; ELECTROCHEMICAL PROPERTIES; CHALLENGES;
D O I
10.1039/c3ta01618h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Single crystalline LiNi1/3Co1/3Mn1/3O2 (LNCM) hexagonal nanobricks with a high percentage of exposed {010} facets are synthesized by using Ni1/3Co1/3Mn1/3(OH)(2) hexagonal nanosheets as both template and precursor, and exhibit excellent high rate performance as a cathode of lithium ion batteries.
引用
收藏
页码:3860 / 3864
页数:5
相关论文
共 36 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   Nanoscale mapping of ion diffusion in a lithium-ion battery cathode [J].
Balke, N. ;
Jesse, S. ;
Morozovska, A. N. ;
Eliseev, E. ;
Chung, D. W. ;
Kim, Y. ;
Adamczyk, L. ;
Garcia, R. E. ;
Dudney, N. ;
Kalinin, S. V. .
NATURE NANOTECHNOLOGY, 2010, 5 (10) :749-754
[3]   Extremely Durable High-Rate Capability of a LiNi0.4Mn0.4Co0.2O2 Cathode Enabled with Single-Walled Carbon Nanotubes [J].
Ban, Chunmei ;
Li, Zheng ;
Wu, Zhuangchun ;
Kirkham, Melanie J. ;
Chen, Le ;
Jung, Yoon Seok ;
Payzant, E. Andrew ;
Yan, Yanfa ;
Whittingham, M. Stanley ;
Dillon, Anne C. .
ADVANCED ENERGY MATERIALS, 2011, 1 (01) :58-62
[4]   LiCoO2 Concaved Cuboctahedrons from Symmetry-Controlled Topological Reactions [J].
Chen, Hailong ;
Wu, Lijun ;
Zhang, Lihua ;
Zhu, Yimei ;
Grey, Clare P. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (02) :262-270
[5]   A breakthrough in the safety of lithium secondary batteries by coating the cathode material with AIPO4 nanoparticles [J].
Cho, J ;
Kim, YW ;
Kim, B ;
Lee, JG ;
Park, B .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (14) :1618-1621
[6]   Single-Crystalline LiMn2O4 Nanotubes Synthesized Via Template-Engaged Reaction as Cathodes for High-Power Lithium Ion Batteries [J].
Ding, Yuan-Li ;
Xie, Jian ;
Cao, Gao-Shao ;
Zhu, Tie-Jun ;
Yu, Hong-Ming ;
Zhao, Xin-Bing .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (02) :348-355
[7]   Room-temperature single-phase Li insertion/extraction in nanoscale LixFePO4 [J].
Gibot, Pierre ;
Casas-Cabanas, Montse ;
Laffont, Lydia ;
Levasseur, Stephane ;
Carlach, Philippe ;
Hamelet, Stephane ;
Tarascon, Jean-Marie ;
Masquelier, Christian .
NATURE MATERIALS, 2008, 7 (09) :741-747
[8]   Challenges for Rechargeable Li Batteries [J].
Goodenough, John B. ;
Kim, Youngsik .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603
[9]   Preparation and electrochemical characterization of single-crystalline spherical LiNi1/3Co1/3Mn1/3O2 powders cathode material for Li-ion batteries [J].
Han, Xiaoyan ;
Meng, Qingfei ;
Sun, Taolei ;
Sun, Jutang .
JOURNAL OF POWER SOURCES, 2010, 195 (10) :3047-3052
[10]   Microscopically porous, interconnected single crystal LiNi1/3Co1/3Mn1/3O2 cathode material for Lithium ion batteries [J].
Huang, Zhen-Dong ;
Liu, Xian-Ming ;
Oh, Sei-Woon ;
Zhang, Biao ;
Ma, Peng-Cheng ;
Kim, Jang-Kyo .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (29) :10777-10784