Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications

被引：3277

作者：

Georgakilas, Vasilios ^{[2
]}

Otyepka, Michal ^{[1
]}

Bourlinos, Athanasios B. ^{[1
]}

Chandra, Vimlesh ^{[3
]}

Kim, Namdong ^{[3
]}

Kemp, K. Christian ^{[3
]}

Hobza, Pavel ^{[3
,4
]}

Zboril, Radek ^{[1
]}

Kim, Kwang S. ^{[3
]}

机构：

[1] Palacky Univ, Reg Ctr Adv Technol & Mat, Dept Phys Chem, Fac Sci, Olomouc 77146, Czech Republic

[2] NCSR Demokritos, Inst Mat Sci, Athens 15310, Greece

[3] Pohang Univ Sci & Technol, Dept Chem, Ctr Superfunct Mat, Pohang 790784, South Korea

[4] Acad Sci Czech Republ, Inst Organ Chem & Biochem, Vvi, CR-16610 Prague 6, Czech Republic

来源：

CHEMICAL REVIEWS | 2012年 / 112卷 / 11期

基金：

新加坡国家研究基金会;

关键词：

EDGE-TO-FACE; CHEMICAL-VAPOR-DEPOSITION; LIQUID-PHASE EXFOLIATION; CATION-PI INTERACTIONS; SINGLE-LAYER GRAPHENE; IN-SITU SYNTHESIS; CARBON NANOTUBES; GRAPHITE OXIDE; EPITAXIAL GRAPHENE; AB-INITIO;

D O I：

10.1021/cr3000412

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Graphene, the two-dimensional sp2-hybridized carbon, is currently, without any doubt, the most intensively studied material. This single-atom-thick sheet of carbon atoms arrayed in a honeycomb pattern is the world's thinnest, strongest, and stiffest material, as well as being an excellent conductor of both heat and electricity. Despite the great application potential, it is worth mentioning that graphene itself possesses zero band gap as well as inertness to reaction, which weakens the competitive strength of grapheme in the field of semiconductors and sensors. The functionalization of pristine graphene sheets with organic functional groups has been developed for several purposes. The main purpose is the dispersibility of graphene in common organic solvents that is usually obtained after attachment of certain organic groups. The dispersion of graphene sheets in organic solvents is a crucial move toward the formation of nanocomposite materials with graphene.

引用

页码：6156 / 6214

页数：59

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