Formation and crystal structure of a polymeric La(H2salen) complex

被引：62

作者：

Xie, WH ^{[1
]}

Heeg, MJ ^{[1
]}

Wang, PG ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 10期

关键词：

D O I：

10.1021/ic9810539

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lanthanide nitrate reacted with H(2)salen at room temperature in MeOH/CH2Cl2 affording a novel polymeric chain complex, [La(H(2)salen)(NO3)(3)(MeOH)(2)](n). The complex displayed an unusual coordination pattern where the imine nitrogen atoms of the H(2)salen molecule were not coordinated. Instead, the two phenolic oxygen atoms, which were often believed to be uncoordinated in previous studies, were found to coordinate respectively to two La atoms.

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页码：2541 / +

页数：4

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