2-Iodoxybenzenesulfamides: new pseudobenziodoxole-based hypervalent iodine reagents

被引：37

作者：

Koposov, AY ^{[1
]}

Litvinov, DN ^{[1
]}

Zhdankin, VV ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Duluth, MN 55812 USA

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 13期

基金：

美国国家卫生研究院;

关键词：

hypervalent iodine; oxidation; benziodoxole IBX;

D O I：

10.1016/j.tetlet.2004.02.053

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A in ides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. these new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzylic alcohols to aldehydes. (C) 2004 Elsevier Ltd. All rights reserved.

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页码：2719 / 2721

页数：3

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