Bis(pi-allyl-6,7-dihydrohimachalene)-alpha,alpha-dichlorodipalladium

被引：12

作者：

ElFirdoussi, L

Allaoud, S

Karim, A

Barrero, AF

Quiros, M

Castanet, Y

Mortreux, A

机构：

[1] UNIV GRANADA,FAC CIENCIAS,DEPT QUIM ORGAN,E-18071 GRANADA,SPAIN

[2] UNIV GRANADA,FAC CIENCIAS,DEPT QUIM INORGAN,E-18071 GRANADA,SPAIN

[3] CATALYSE HETEROGENE & HOMOGENE LAB,CNRS,UA 402,VILLENEUVE DASCQ,FRANCE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270196015557

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of trans-6,7-dihydrohimachalene [(1R,2R,7R)-2,6,6,9-tetramethylbicyclo[5.4.0]deca-8-ene] with palladium(II) chloride gives bis(chloro)-bridged cyclopalladated dimers, [Pd2Cl2(C15H25)(2)], with high regio- and stereoselectivity. The molecule displays crystallographic twofold symmetry and adopts a butterfly shape (the Pd2Cl2 unit is the 'body' and the organic ligands are the 'wings'). The methyl group on the asymmetric C atom points to the side in which the Pd2Cl2 unit is placed.

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页码：710 / 712

页数：3

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