A new carbonate bridged tetranuclear zinc(II) complex of an asymmetric tetrapodal compartmental ligand

被引：27

作者：

Adams, H ^{[1
]}

Bradshaw, D ^{[1
]}

Fenton, DE ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield, S Yorkshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 23期

关键词：

D O I：

10.1039/b108432c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A zinc(II) complex of the asymmetric tetrapodal proligand 2-{[bis(2-pyridinylmethyl)amino]methyl}-6-[{[(2-hydroxyphenyl)methyl](2- pyridinylmethyl)amino}methyl]-4-methylphenol reacts with carbon dioxide to give the tetranuclear zinc(II) complex [Zn4L2(CO3)](BF4)(2). 5CH(3)OH . 4H(2)O; the crystal structure of this complex revealed an unusual mu (3)-binding mode of the carbonate to one mononuclear zinc atom and a dinuclear pair of zinc atoms.

引用

页码：3407 / 3409

页数：3

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