PCR-like cascade reactions in the context of an allosteric enzyme mimic

被引：111

作者：

Yoon, Hyo Jae

Mirkin, Chad A. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 35期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ja804076q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A supramolecular allosteric catalyst that exhibits a PCR-like cascade reaction is reported. The complex is triggered by a reaction with an acetate ion, which turns on a catalytic cascade that exponentially increases acetate ion concentration through an acyl transfer reaction.

引用

收藏

页码：11590 / +

页数：3

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