Effect of N-substitution in naphthalenediimides on the electrochemical performance of organic rechargeable batteries

被引:79
作者
Kim, Dong Jun [1 ]
Je, Sang Hyun [2 ]
Sampath, Srinivasan [2 ]
Choi, Jang Wook [2 ]
Coskun, Ali [2 ,3 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Grad Sch Energy Environm Water & Sustainabil WCU, Taejon 305701, South Korea
[3] Korea Adv Inst Sci & Technol, Dept Chem & Nano Century, KAIST Inst, Taejon 305701, South Korea
来源
RSC ADVANCES | 2012年 / 2卷 / 21期
关键词
LITHIUM BATTERIES; STORAGE MATERIALS; ION BATTERY; POLYMERS;
D O I
10.1039/c2ra21239k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have demonstrated that even small structural variations on the imide nitrogens of naphthalenediimides bearing identical Li-ion binding sites can cause dramatic effects in the performance of organic rechargeable batteries. In particular, naphthalenedimide dilithium salt showed excellent cycling with a capacity of 130 mA h g(-1) at potentials as high as 2.5 V vs. Li/Li+.
引用
收藏
页码:7968 / 7970
页数:3
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