Aqueous phase oxidation of methane with hydrogen peroxide catalyzed by Di-iron-substituted silicotungstate

被引:36
作者
Mizuno, N [1 ]
Seki, Y [1 ]
Nishiyama, Y [1 ]
Kiyoto, I [1 ]
Misono, M [1 ]
机构
[1] Univ Tokyo, Grad Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
关键词
D O I
10.1006/jcat.1999.2455
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The title reaction was catalyzed by a water-soluble potassium salt of di-iron-substituted silicotungstate, gamma-SiW10{Fe(OH2)}(2)O-38(6-), mono- and tri-iron-substituted silicotungstates being much less active and nonselective for the oxidation. (C) 1999 Academic Press.
引用
收藏
页码:550 / 552
页数:3
相关论文
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