Thiol-Ene Reaction for the Synthesis of Multifunctional Branched Organosilanes

被引：86

作者：

Rissing, Christiana ^{[1
]}

Son, David Y. ^{[1
]}

机构：

[1] So Methodist Univ, Dept Chem, Dallas, TX 75275 USA

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 20期

关键词：

D O I：

10.1021/om8003527

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Various commercially available thiols react photochemically with tetravinylsilane to give the corresponding tetrasubstituted thioether compounds. The reactions are conducted in air using typical borosilicate glassware. Yields range from 64 to 100%, and purification steps, if necessary, involve simple precipitation or extraction steps. Thiol addition occurs predominantly to give the anti-Markovnikov product; amounts of Markovnikov addition range from 1 to 5%.

引用

页码：5394 / 5397

页数：4

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