Novel Ti6, Zr3, and Zr6 complexes from branched polyynes and titanocene as well as zirconocene

被引：24

作者：

Pellny, PM ^{[1
]}

Burlakov, VV ^{[1
]}

Baumann, W ^{[1
]}

Spannenberg, A ^{[1
]}

Kempe, R ^{[1
]}

Rosenthal, U ^{[1
]}

机构：

[1] Univ Rostock, Inst Organ Katalyseforsch, D-18055 Rostock, Germany

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 15期

关键词：

D O I：

10.1021/om9901980

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the branched polyynes tris(tert-butylbutadiynyl)benzene (1,3,5-((BuC)-Bu-t=CC=C)(3)C6H3) (1) with the metallocene sources Cp2Ti(eta(2)-Me3SiC=CSiMe3) (2) and Cp2Zr(THF)(eta(2)-Me3SiC=CSiMe3) (3; THF = tetrahydrofuran) led to diverse novel organometallic Ti-6 (4), Zr-3 (5), and Zr-6 (6) complexes depending on the metals, the polyynes, and the stoichiometries employed in. the conversions. The new complexes have been characterized spectroscopically. Additionally X-ray crystal structure analyses were performed for 4 and 6.

引用

页码：2906 / 2909

页数：4

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