Addition reactions of the novel mononuclear dithio-o -carboranylcobalt(III) complex (η5-C5H5)Co(η2- S2C2B10H10)

被引：116

作者：

Kim, DH

Ko, JJ

Park, K

Cho, SG

Kang, SO

机构：

[1] Korea Univ, Dept Chem, Chochiwon, Chungnam, South Korea

[2] Seoul City Univ, Dept Chem Engn, Seoul 130743, South Korea

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 15期

关键词：

D O I：

10.1021/om990269v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mononuclear 16-electron dithio-o-carboranylcobalt(III) complex CpCo(S2C2B10H10) (2) was obtained by the reaction of CpCo(CO)I-2 with dilithium dithio-o-carborane, Li-2[S2C2B10H10] (1). Complex 2 reacts with a variety of substrates such as CpCo(C2H2)(2), alkynes, and a diazoalkane, generating a new class of dithio-o-carboranylcobalt(III) compounds incorporating a CpCo unit and alkene and alkylidene ligands.

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页码：2738 / 2740

页数：3

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