Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst

被引：187

作者：

Chen, K

Que, L

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 15期

关键词：

D O I：

10.1039/a901678c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The incorporation of O-18 from (H2O)-O-18 into the product of stereospecific alkane hydroxylation by [Fe-II(bpmen)-(CH3CN)(2)](ClO4)(2)-H2O2 provides the first strong evidence for the participation of a high-valent iron-oxo species in the mechanism of a non-heme iron catalyst.

引用

页码：1375 / 1376

页数：2

共 39 条

[1] A MECHANISTIC PROBE FOR OXYGEN ACTIVATION BY METAL-COMPLEXES AND HYDROPEROXIDES AND ITS APPLICATION TO ALKANE FUNCTIONALIZATION BY [FE(III)CL(2)TRIS(2-PYRIDINYLMETHYL)AMINE](+)BF4-
ARENDS, IWCE
INGOLD, KU
WAYNER, DDM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (16) : 4710 - 4711
[2] Origin of the oxygen atom in C-H bond oxidations catalyzed by a water-soluble metalloporphyrin
Balahura, RJ
Sorokin, A
Bernadou, J
Meunier, B
[J]. INORGANIC CHEMISTRY, 1997, 36 (16) : 3488 - 3492
[3] 'Oxo-hydroxo tautomerism' as useful mechanistic tool in oxygenation reactions catalysed by water-soluble metalloporphyrins
Bernadou, J
Meunier, B
[J]. CHEMICAL COMMUNICATIONS, 1998, (20) : 2167 - 2173
[4] IRON(II) COMPLEXES OF POLYDENTATE AMINOPYRIDYL LIGANDS AND AN EXCHANGEABLE 6TH LIGAND REACTIONS WITH PEROXIDES - CRYSTAL-STRUCTURE OF [FEL(1)(H2O)][PF6](2)CENTER-DOT-H2O [L(1)=N,N'-BIS(6-METHYL-2-PYRIDYLMETHYL)-N,N'-BIS(2-PYRIDYLMETHYL)ETHANE-1,2-DIAMINE]
BERNAL, I
JENSEN, IM
JENSEN, KB
MCKENZIE, CJ
TOFTLUND, H
TUCHAGUES, JP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (22): : 3667 - 3675
[5] BIOMIMETIC OXIDATION STUDIES .8. STRUCTURE OF A NEW MMO ACTIVE-SITE MODEL, [FE2O(H2O)2(TRIS(1-METHYLIMIDAZOL-2-YL)METHYL)AMINE)2]4+, AND ROLE OF THE AQUA LIGAND IN ALKANE FUNCTIONALIZATION REACTIONS
BUCHANAN, RM
CHEN, S
RICHARDSON, JF
BRESSAN, M
FORTI, L
MORVILLO, A
FISH, RH
[J]. INORGANIC CHEMISTRY, 1994, 33 (15) : 3208 - 3209
[6] A novel pentadentate ligand 2,6-bis[methoxybis(2-pyridyl)methyl]pyridine L for mononuclear iron(II) and manganese(II) compounds; Synthesis and crystal structures of [FeL(MeCN)][ClO4](2) and [(MnL(H2O)][ClO4](2)
deVries, ME
LaCrois, RM
Roelfes, G
Kooijman, H
Spek, AL
Hage, R
Feringa, BL
[J]. CHEMICAL COMMUNICATIONS, 1997, (16) : 1549 - 1550
[7] BIOMIMETIC OXIDATION STUDIES .5. MECHANISTIC ASPECTS OF ALKANE FUNCTIONALIZATION WITH FE,FE2O, AND FE4O2 COMPLEXES IN THE PRESENCE OF HYDROGEN-PEROXIDE
FISH, RH
KONINGS, MS
OBERHAUSEN, KJ
FONG, RH
YU, WM
CHRISTOU, G
VINCENT, JB
COGGIN, DK
BUCHANAN, RM
[J]. INORGANIC CHEMISTRY, 1991, 30 (15) : 3002 - 3006
[8] MECHANISM OF OXYGENATION OF CIS-STILBENE BY IRON BLEOMYCIN
HEIMBROOK, DC
CARR, SA
MENTZER, MA
LONG, EC
HECHT, SM
[J]. INORGANIC CHEMISTRY, 1987, 26 (23) : 3835 - 3836
[9] Raman evidence for a weakened O-O bond in mononuclear low-spin iron(III)- hydroperoxides
Ho, RYN
Roelfes, G
Feringa, BL
Que, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (01) : 264 - 265
[10] Formation and reactivity of a peroxide adduct of iron(III) complexes containing substituted phenol derivatives
Ito, S
Suzuki, M
Kobayashi, T
Itoh, H
Harada, A
Ohba, S
Nishida, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (12): : 2579 - 2580

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