A novel pentadentate ligand 2,6-bis[methoxybis(2-pyridyl)methyl]pyridine L for mononuclear iron(II) and manganese(II) compounds; Synthesis and crystal structures of [FeL(MeCN)][ClO4](2) and [(MnL(H2O)][ClO4](2)

被引:76
作者
deVries, ME
LaCrois, RM
Roelfes, G
Kooijman, H
Spek, AL
Hage, R
Feringa, BL
机构
[1] UNIV GRONINGEN,DEPT ORGAN & MOL INORGAN CHEM,NL-9747 AG GRONINGEN,NETHERLANDS
[2] UNIV UTRECHT,BIJVOET CTR BIOMOL RES,NL-3584 CH UTRECHT,NETHERLANDS
[3] UNILEVER RES LABS VLAARDINGEN,NL-3130 AC VLAARDINGEN,NETHERLANDS
关键词
D O I
10.1039/a702804k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel pentadentate ligand L is capable of stabilising Fe-II and Mn-II centres, the first of which gives a transient iron hydroperoxide species upon treatment with hydrogen peroxide.
引用
收藏
页码:1549 / 1550
页数:2
相关论文
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