Generation of 1-azapentadienyl anion from N-(tert-butyldimethylsilyl)-3-buten-1-amine

被引：12

作者：

Jacobson, MA ^{[1
]}

Williard, PG ^{[1
]}

机构：

[1] Brown Univ, Dept Chem, Providence, RI 02912 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 11期

关键词：

D O I：

10.1021/jo0162336

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-(tert-Butyldimethylsilyl)-3-buten-1-amine undergoes allylic deprotonation at the 2-position when exposed to 2 equiv of nBuLi in THE This allylic anion undergoes lithium hydride elimination to generate a 1-azapentadienyl anion. The anion is generated cleanly and completely.

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页码：3915 / 3918

页数：4

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