A novel chemiluminescence flow-through sensor for the determination of analgin

被引:27
作者
Huang, YM
Zhang, C
Zhang, XR
Zhang, ZJ [1 ]
机构
[1] SW Normal Univ, Dept Chem, Chongqing 400715, Peoples R China
[2] Nanjing Univ, Dept Chem, Nanjing 210008, Peoples R China
[3] Shaanxi Normal Univ, Dept Chem, Xian 710062, Peoples R China
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1999年 / 365卷 / 04期
关键词
D O I
10.1007/s002160051506
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A novel chemiluminescence (CL) flow-through sensor for the determination of analgin with flow-injection analysis (FIA) based on the auto-oxidation of analgin in the presence of Tween 80 sensitized by Rhodamine 6G immobilized on a cation-exchange column is described. This sensor responds linearly to the analgin concentration in the range of 0.4 similar to 10 mg/L, with a detection limit (30) of 0.15 mg/L. A complete analysis, including sampling and washing, takes 1 min with a relative standard deviation of < 5%. The sensor is stable for over 200 determinations and has successfully been applied to the determination of analgin in pharmaceutical preparations.
引用
收藏
页码:381 / 383
页数:3
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