A synthetic route to borylene-bridged poly(ferrocenylene)s

被引：130

作者：

Heilmann, JB

Scheibitz, M

Qin, Y

Sundararaman, A

Jäkle, F

Kretz, T

Bolte, M

Lerner, HW

Holthausen, MC

Wagner, M

机构：

[1] New Jersey Inst Technol, Dept Chem, Newark, NJ 07102 USA

[2] Goethe Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 06期

关键词：

boranes; density functional calculations; ferrocene; organic-inorganic hybrid composites; polymers;

D O I：

10.1002/anie.200503515

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron chains: The highly soluble, ferrocene-containing polymer [-fc-B(Mes)-]n (fc = Fe(C5H4)2, Mes = mesityl), with an average chain length of about 16 repeat units (n = 16), is readily accessible by a novel polycondensation reaction starting from fc(BBr2)2 and HSiEt3 (see scheme). The polymer contains three-coordinate boron centers, which are well-suited for the promotion of electron delocalization along the polymer chain. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：920 / 925

页数：6

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