Catalytic asymmetric synthesis of glycidic amides via chiral sulfur ylides

被引:30
作者
Imashiro, R [1 ]
Yamanaka, T [1 ]
Seki, M [1 ]
机构
[1] Tanabe Seiyaku Co Ltd, Discovery Res Lab, Yodogawa Ku, Osaka 5328505, Japan
关键词
D O I
10.1016/S0957-4166(99)00289-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of diazoacetamides with aromatic aldehydes in the presence of 20 mol% of chiral binaphthylsulfide and 10 mol% of copper(II) acetylacetonate gave chiral glycidic amides with up to 64% ee. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2845 / 2851
页数:7
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