Atomic-scale analysis of the oxygen configuration at a SrTiO3 dislocation core -: art. no. 225506

被引:110
作者
Jia, CL [1 ]
Thust, A
Urban, K
机构
[1] Forschungszentrum Julich, Inst Solid State Res, D-52425 Julich, Germany
[2] Forschungszentrum Julich, Ernst Ruska Ctr Microscopy & Spect Elect, ERC, D-52425 Julich, Germany
关键词
D O I
10.1103/PhysRevLett.95.225506
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The atomic structure of a SrTiO3 dislocation is revealed directly by phase-retrieval electron microscopy. In particular, atomic columns of light oxygen are observed simultaneously with the columns of considerably heavier Sr and Ti. A distinct structural modification of the oxygen octahedra at the dislocation core as well as a significant nonstoichiometry, including a deficiency of oxygen, are observed. Deviations from the bulk chemical concentration are quantified column by column by means of structure modeling and quantum-mechanical simulations of the electron scattering process.
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页数:4
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