Conjugated Polymers from Naphthalene Bisimide

被引：321

作者：

Guo, Xugang ^{[1
]}

Watson, Mark D. ^{[1
]}

机构：

[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 23期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ol801918y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stille coupling of regioisomerically pure dibromonaphthalene bisimides (NBI) with various stannylated thiophene-based monomers yields (very) high molecular weight donor-acceptor conjugated polymers. Electrochemical and optical absorption measurements reveal that LUMO energies are essentially invariant and dictated by the NBI units, while HOMO energies are dictated by the thienyl comonomers. Optical energy gaps ranging from 1.7 to 1.1 eV are thus obtained. The polymers are also characterized by differential scanning calorimetry and fiber WAXD.

引用

收藏

页码：5333 / 5336

页数：4

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