Preparation and photocatalytic activity of Cu2+-doped TiO2/SiO2

被引:49
作者
Chen, Ru-fen [1 ]
Zhang, Cui-xuan [1 ]
Deng, Juan [1 ]
Song, Guo-qiang [1 ]
机构
[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China
关键词
nanostructured TiO2; SiO2; particles; layer-by-layer assembly; Cu2+-doped; photocatalytic activity; TIO2; THIN-FILMS; MESOPOROUS TIO2; TEMPERATURE; NANOPARTICLES; TITANIA;
D O I
10.1016/S1674-4799(09)60037-6
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
Cu2+-doped nanostructured TiO2-coated SiO2 (TiO2/SiO2) particles were prepared by the layer-by-layer assembly technique and their photocatalytic property was studied. TiO2 colloids were synthesized by the sol-gel method using TiOSO4 as a precursor. The experimental results showed that TiO2 nanopowders on the surface of SiO2 particles were well distributed and compact. The amount of TiO2 increased with the increase in coating layers. The shell structure appeared to be composed of anatase titania nanocrystals at 550 degrees C. The 2-layer coated TiO2 particles on the surface showed a higher degradation rate compared with all the different-layer samples. The photocatalytic activity of Cu2+-doped TiO2/SiO2 was higher than that of undoped TiO2/SiO2. The optimum dopant content was about 0.10wt%.
引用
收藏
页码:220 / 225
页数:6
相关论文
共 23 条
[1]
The effect of calcination temperature on the crystallinity of TiO2 nanopowders [J].
Chen, YF ;
Lee, CY ;
Yeng, MY ;
Chiu, HT .
JOURNAL OF CRYSTAL GROWTH, 2003, 247 (3-4) :363-370
[2]
Large scale studies in solar catalytic wastewater treatment [J].
Dillert, R ;
Cassano, AE ;
Goslich, R ;
Bahnemann, D .
CATALYSIS TODAY, 1999, 54 (2-3) :267-282
[3]
FTIR and XPS investigation of Er-doped SiO2-TiO2 films [J].
Fang, Q ;
Meier, M ;
Yu, JJ ;
Wang, ZM ;
Zhang, JY ;
Wu, JX ;
Kenyon, A ;
Hoffmann, P .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2003, 105 (1-3) :209-213
[4]
SiO2/TiO2 thin films with variable refractive index prepared by ion beam induced and plasma enhanced chemical vapor deposition [J].
Gracia, F ;
Yubero, F ;
Holgado, JP ;
Espinos, JP ;
Gonzalez-Elipe, AR ;
Girardeau, T .
THIN SOLID FILMS, 2006, 500 (1-2) :19-26
[5]
GRATZEL M, 1990, J PHYS CHEM-US, V94, P2566, DOI 10.1021/j100369a064
[6]
Fabrication and optical characterization of a TiO2 thin film on a silica microsphere [J].
Haraguchi, M ;
Komatsu, F ;
Tajiri, K ;
Okamoto, T ;
Fukui, M ;
Kato, S .
SURFACE SCIENCE, 2004, 548 (1-3) :59-66
[7]
Conductive and transparent multilayer films for low-temperature-sintered mesoporous TiO2 electrodes of dye-sensitized solar cells [J].
Ito, S ;
Takeuchi, T ;
Katayama, T ;
Sugiyama, M ;
Matsuda, M ;
Kitamura, T ;
Wada, Y ;
Yanagida, S .
CHEMISTRY OF MATERIALS, 2003, 15 (14) :2824-2828
[8]
Enhanced photocatalytic activity of Ce3+-TiO2 for 2-mercaptobenzothiazole degradation in aqueous suspension for odour control [J].
Li, FB ;
Li, XZ ;
Hou, MF ;
Cheah, KW ;
Choy, WCH .
APPLIED CATALYSIS A-GENERAL, 2005, 285 (1-2) :181-189
[9]
SONAWANE RS, 2002, MATER CHEM PHYS, V77, P77
[10]
Preparation and characteristics of core-shell rutile titania/wollastonite at room temperature [J].
Tao, NN ;
Zhao, JZ ;
Guo, YP ;
Jiang, YQ ;
Ding, XF ;
Wang, ZC .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 84 (01) :58-62