Shape selective solvothermal synthesis of SnS: Role of ethylenediamine-water solvent system

被引:39
作者
Panda, SK [1 ]
Gorai, S [1 ]
Chaudhuri, S [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Mat Sci, Kolkata 700032, W Bengal, India
来源
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2006年 / 129卷 / 1-3期
关键词
SnS; solvent effect; nanostructures; UV-vis spectroscopy;
D O I
10.1016/j.mseb.2005.12.014
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanocrystalline SnS with different morphologies has been successfully synthesized over Sn metal foils via a solvothermal route by using ethylenediamine, water and their mixture as the solvents. XRD studies indicated that in all the cases pure SnS phase exists. TEM studies revealed well crystallinity of the nanostructures. Oxidation of the metal foil played an important role in the formation of SnS nanostructures. Optical band gap of the samples were found to be similar to 1.3 eV. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:265 / 269
页数:5
相关论文
共 26 条
[1]   THE PREPARATION AND THE ELECTRICAL AND OPTICAL PROPERTIES OF SNS CRYSTALS [J].
ALBERS, W ;
HAAS, C ;
VANDERMAESEN, F .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1960, 15 (3-4) :306-310
[2]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[3]   Shape-selected synthesis of nanocrystalline SnS in different alkaline media [J].
An, CH ;
Tang, KB ;
Jin, Y ;
Liu, QC ;
Chen, XY ;
Qian, YT .
JOURNAL OF CRYSTAL GROWTH, 2003, 252 (04) :581-586
[4]   Single-nanowire electrically driven lasers [J].
Duan, XF ;
Huang, Y ;
Agarwal, R ;
Lieber, CM .
NATURE, 2003, 421 (6920) :241-245
[5]   Crossed nanotube junctions [J].
Fuhrer, MS ;
Nygård, J ;
Shih, L ;
Forero, M ;
Yoon, YG ;
Mazzoni, MSC ;
Choi, HJ ;
Ihm, J ;
Louie, SG ;
Zettl, A ;
McEuen, PL .
SCIENCE, 2000, 288 (5465) :494-497
[6]   Shape selective solvothermal synthesis of copper sulphides: role of ethylenediamine-water solvent system [J].
Gorai, S ;
Ganguli, D ;
Chaudhuri, S .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 116 (02) :221-225
[7]   Synthesis of 1D Cu2S with tailored morphology via single and mixed ionic surfactant templates [J].
Gorai, S ;
Ganguli, D ;
Chaudhuri, S .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 88 (2-3) :383-387
[8]   Morphology evolution of SnS nanocrystals: from 3D urchin-like architectures to 1D nanostructures [J].
Hu, HM ;
Yang, BJ ;
Zeng, JH ;
Qian, YT .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 86 (01) :233-237
[9]  
Hulliger F., 1976, Structural Chemistry of Layer-Type Phases
[10]  
Series: Physics and Chemistry of Materials with Layered Structures