Methyltrioxorhenium-catalyzed oxidation of secondary and primary amines with hydrogen peroxide

被引：69

作者：

Yamazaki, S

机构：

[1] Toyama Industrial Technology Center, Takaoka, Toyama 933

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1997年 / 70卷 / 04期

关键词：

D O I：

10.1246/bcsj.70.877

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The methyltrioxorhenium-catalyzed oxidation of secondary amines and primary amines with hydrogen peroxide has been carried out. The oxidation of secondary amines afforded nitrones in good-to-excellent yield. Benzylamines were selectively oxidized to oximes, while general primary alkylamines possessing the alpha-C-H bond gave mixtures of oximes, nitroso dimers, and azoxy compounds.

引用

页码：877 / 883

页数：7

共 56 条

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