Synthesis and structure of the two-dimensional bimetallic oxide [H4tphz]3[{Zn2(tphz)(H2O)4}{Mo5O15(O3PCH2CH2PO3)}4] • 14H2O:: the hydrothermal conversion of tetra-2-pyridylpyrazine to tetrapyrido [2,3-a:3′,2′-c:2",3"-h:3"′,2"′-j]phenazine (tphz)

被引：20

作者：

Burkholder, E ^{[1
]}

Zubieta, J ^{[1
]}

机构：

[1] Syracuse Univ, Ctr Sci & Technol, Dept Chem, Syracuse, NY 13244 USA

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 04期

基金：

美国国家科学基金会;

关键词：

hydrothermal synthesis; bimetallic oxide; molybdophosphonate cluster; network oxide;

D O I：

10.1016/j.ica.2003.09.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of (NH4)(6)Mo7O24.4H(2)O, ZnSO4.7H(2)O, tetra-2-pyridylpyrazine, ethylenediphosphonic acid, H2O and HF at 170 degreesC for 96 h yields yellow crystals of [H(4)tphz](3)[{Zn-2(tphz)(H2O)(4)} {Mo5O15(O3PCH2CH2PO3)}(4)].14H(2)O (1.14H(2)O) (tphz = tetrapyrido[2,3-a:3',2'-c:2",13"-h:3"',2"' j]phenazine (tphz)). The structure of 1 consists of two-dimensional networks constructed from chains of {Mo5O15(O3PR)(2)}(4-) clusters tethered through the ethylene bridges of the diphosphonate ligands, which are in turn crosslinked through the {Zn-2(tphz)(H2O)(4)}(4divided by) subunits. This connectivity generates intralamellar cavities which are occupied by the tetraprotonated H(4)tphz(4divided by) cations. A curious feature of the chemistry is the hydrothermal conversion of the tetra-2-pyridylpyrazine starting material to tphz. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：1229 / 1235

页数：7

共 84 条

[1]

Barrer RM., 1982, HYDROTHERMAL CHEM ZE

[2] Control of interpenetrating copper(I) adamantoid networks: Synthesis and structure of {[Cu(bpe)(2)]BF4}(n) [J].

Blake, AJ ;

Champness, NR ;

Chung, SSM ;

Li, WS ;

Schroder, M .

CHEMICAL COMMUNICATIONS, 1997, (11) :1005-1006

[3]

Bonhote P, 1997, SYNLETT, P897

[4]

BONHOTE P, 1998, CHEM COMMUN, V8, P885

[5]

Buchner W., 1989, Industrial inorganic chemistry

[6] Solid state coordination chemistry: One-, two-, and three-dimensional materials constructed from molybdophosphonate subunits linked through binuclear copper tetra-2-pyridylpyrazine groups [J].

Burkholder, E ;

Golub, V ;

O'Connor, CJ ;

Zubieta, J .

INORGANIC CHEMISTRY, 2003, 42 (21) :6729-6740

[7] Solid state coordination chemistry:: construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(II) complexes.: The syntheses and structures of [{Cu2( tpypyz)(H2O)2}(Mo5O15)(HOPO3)2]•nH2O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine] [J].

Burkholder, E ;

Zubieta, J .

CHEMICAL COMMUNICATIONS, 2001, (20) :2056-2057

[8]

BURKHOLDER E, 2003, IN PRESS INORG CHEM, V42

[9] A three-dimensional, three-connected cubic network of the SrSi2 topological type in coordination polymer chemistry: [Ag(hmt)](PF6)center dot H2O (hmt=hexamethylenetetraamine) [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM ;

Sironi, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (51) :12861-12862

[10] Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co5(bpe)9(H2O)8(SO4)4](SO4)•14H2O [bpe=1,2-bis(4-pyridyl)ethane] [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM ;

Rizzato, S .

CHEMICAL COMMUNICATIONS, 2000, (14) :1319-1320

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