Vibrational spectra of selenium nanoparticles dispersed in a polymer

被引:39
作者
Rajalakshmi, M [1 ]
Arora, AK [1 ]
机构
[1] Indira Gandhi Ctr Atom Res, Div Mat Sci, Kalpakkam 603102, Tamil Nadu, India
来源
NANOSTRUCTURED MATERIALS | 1999年 / 11卷 / 03期
关键词
D O I
10.1016/S0965-9773(99)00194-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Vibrational spectra of selenium nanoparticles dispersed in a polymer are studied using Raman scattering. Confined optical and acoustic phonons are investigated. Asymmetric line-shape of the confined optical phonons is fitted using the confinement model which takes into account the phonon dispersion curves. A wavelength selectivity of confined optical phonons is also observed. The low frequency Raman spectrum exhibits peaks that can be assigned to the spheroidal modes of the particles of size around 3 nm, consistent with that used for confined optical phonon line-shape analysis. (C) 1999 Acta Metallurgica Inc.
引用
收藏
页码:399 / 405
页数:7
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