Flower-like NiO structures: Controlled hydrothermal synthesis and electrochemical characteristic

被引:28
作者
Chai, Hui [1 ,2 ]
Chen, Xuan [1 ,2 ]
Jia, Dianzeng [1 ,2 ]
Bao, Shujuan [1 ,2 ]
Zhou, Wanyong
机构
[1] Xinjiang Univ, Minist Educ, Key Lab Clean Energy Mat & Technol, Urumqi 830046, Xinjiang, Peoples R China
[2] Xinjiang Univ, Inst Appl Chem, Key Lab Adv Funct Mat, Urumqi 830046, Xinjiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Oxides; Electrochemical properties; Energy storage; REDUCED GRAPHENE OXIDE; NICKEL-OXIDE; ACTIVATED CARBONS; ANODE MATERIAL; COMPOSITE; ELECTRODE; CAPACITANCE; DEPOSITION; NANOSTRUCTURES; TEMPERATURE;
D O I
10.1016/j.materresbull.2012.08.033
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Flower-like porous NiO was obtained by thermal decomposition of the precursor prepared by a hydrothermal process with hexamethylenetetramine and polyethylene glycol as hydrolysis-controlling agent and surfactant, respectively. The morphology and microstructure of as-synthesized NiO were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The resulting structures of NiO exhibited porous like petal building blocks. The electrochemical measurements' results demonstrated that flower-like porous NiO has high capacity (340 F g(-1)) with excellent cycling performance as electrode materials for electrochemical capacitors, which may be attributed to the unique structure of NiO. The results indicated that NiO with novel porous structure has been attractive for practical and large-scale applications in electrochemical capacitors. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3947 / 3951
页数:5
相关论文
共 34 条
[1]   Nano-architectured Co(OH)2 electrodes constructed using an easily-manipulated electrochemical protocol for high-performance energy storage applications [J].
Chang, Jeng-Kuei ;
Wu, Chih-Ming ;
Sun, I-Wen .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (18) :3729-3735
[2]   Electrochemical capacitive properties of cadmium oxide films [J].
Chang, Jinho ;
Mane, Rajaram S. ;
Ham, Dukho ;
Lee, Wonjoo ;
Cho, Byng Won ;
Lee, Joong Ki ;
Han, Sung-Hwan .
ELECTROCHIMICA ACTA, 2007, 53 (02) :695-699
[3]   Synthesis and characterization of mesoporous Mn-Ni oxides for supercapacitors [J].
Fang, Dao-Lai ;
Wu, Bing-Cai ;
Yan, Yong ;
Mao, Ai-Qin ;
Zheng, Cui-Hong .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (01) :135-142
[4]   Incorporation of homogeneous, nanoscale MnO2 within ultraporous carbon structures via self-limiting electroless deposition:: Implications for electrochemical capacitors [J].
Fischer, Anne E. ;
Pettigrew, Katherine A. ;
Rolison, Debra R. ;
Stroud, Rhonda M. ;
Long, Jeffrey W. .
NANO LETTERS, 2007, 7 (02) :281-286
[5]   Graphene Nanosheet/Ni2+/Al3+ Layered Double-Hydroxide Composite as a Novel Electrode for a Supercapacitor [J].
Gao, Zan ;
Wang, Jun ;
Li, Zhanshuang ;
Yang, Wanlu ;
Wang, Bin ;
Hou, Mengjie ;
He, Yang ;
Liu, Qi ;
Mann, Tom ;
Yang, Piaoping ;
Zhang, Milin ;
Liu, Lianhe .
CHEMISTRY OF MATERIALS, 2011, 23 (15) :3509-3516
[6]   Chemically grown, porous, nickel oxide thin-film for electrochemical supercapacitors [J].
Inamdar, A. I. ;
Kim, YoungSam ;
Pawar, S. M. ;
Kim, J. H. ;
Im, Hyunsik ;
Kim, Hyungsang .
JOURNAL OF POWER SOURCES, 2011, 196 (04) :2393-2397
[7]   Tuning of Capacitance Behavior of NiO Using Anionic, Cationic, and Nonionic Surfactants by Hydrothermal Synthesis [J].
Justin, P. ;
Meher, Sumanta Kumar ;
Rao, G. Ranga .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (11) :5203-5210
[8]   Microstructure and Pseudocapacitive Properties of Electrodes Constructed of Oriented NiO-TiO2 Nanotube Arrays [J].
Kim, Jae-Hun ;
Zhu, Kai ;
Yan, Yanfa ;
Perkins, Craig L. ;
Frank, Arthur J. .
NANO LETTERS, 2010, 10 (10) :4099-4104
[9]   Effect of nonstoichiometry of nickel oxides on their supercapacitor behavior [J].
Lee, SH ;
Tracy, CE ;
Pitts, JR .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (10) :A299-A301
[10]   Porous nickel oxide/nickel films for electrochemical capacitors [J].
Liu, KC ;
Anderson, MA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :124-130