Thioketone spin traps as mediating agents for free radical polymerization processes

被引：56

作者：

Toy, AA

Chaffey-Millar, H

Davis, TP

Stenzel, MH

Izgorodina, EI

Coote, ML ^{[1
]}

Barner-Kowollik, C

机构：

[1] Australian Natl Univ, Res Sch Chem, ARC Ctr Excellence Free Rad Chem & Biotechnol, Canberra, ACT 0200, Australia

[2] Univ New S Wales, Ctr Adv Macromol Design, Sch Chem Engn & Ind Chem, Sydney, NSW 2052, Australia

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 08期

关键词：

D O I：

10.1039/b515561d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thioketones are demonstrated to be suitable agents for controlling free radical polymerization processes: the polymerizations carry ( pseudo) living characteristics indicating that the control process is induced by a persistent radical effect.

引用

页码：835 / 837

页数：3

共 18 条

[1] Spin trapping with phosphonothionesters. Part VI. Phosphoryl- and thiophosphoryl-thionformates [J].

Alberti, A ;

Benaglia, M ;

Hudson, A ;

Macciantelli, D ;

Masson, S .

RESEARCH ON CHEMICAL INTERMEDIATES, 2001, 27 (06) :659-668

[2] SPIN TRAPPING WITH THIOCARBONYL COMPOUNDS [J].

ALBERTI, A ;

BENAGLIA, M ;

BONINI, BF ;

PEDULLI, GF .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1988, 84 :3347-3358

[3] RAFTing down under: Tales of missing radicals, fancy architectures, and mysterious holes [J].

Barner-Kowollik, C ;

Davis, TP ;

Heuts, JPA ;

Stenzel, MH ;

Vana, P ;

Whittaker, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (03) :365-375

[4] Kinetic investigations of reversible addition fragmentation chain transfer polymerizations: Cumyl phenyldithioacetate mediated homopolymerizations of styrene and methyl methacrylate [J].

Barner-Kowollik, C ;

Quinn, JF ;

Nguyen, TLU ;

Heuts, JPA ;

Davis, TP .

MACROMOLECULES, 2001, 34 (22) :7849-7857

[5]

Brandrup J., POLYM HDB

[6] Ab initio evidence for slow fragmentation in RAFT polymerization [J].

Coote, ML ;

Radom, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (06) :1490-1491

[7]

Corpart P., 1998, Patent No. 9858974

[8]

EPENSON JH, 1992, ACCOUNTS CHEM RES, V25, P222

[9] Consistent experimental and theoretical evidence for long-lived intermediate radicals in living free radical polymerization [J].

Feldermann, A ;

Coote, ML ;

Stenzel, MH ;

Davis, TP ;

Barner-Kowollik, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (48) :15915-15923

[10] Kinetics of living radical polymerization [J].

Goto, A ;

Fukuda, T .

PROGRESS IN POLYMER SCIENCE, 2004, 29 (04) :329-385

← 1 2 →