Rhodium-catalyzed tandem vinylcyclopropanation of strained alkenes

被引：53

作者：

Tseng, NW ^{[1
]}

Mancuso, J ^{[1
]}

Lautens, M ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Davenport Res Labs, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 16期

关键词：

D O I：

10.1021/ja060877j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication reports an unusual rhodium-catalyzed 1,6-addition of a dienylboronate ester to highly strained alkenes. The resulting vinylcyclopropane-fused tricyclic products were produced in moderate to good yields. Preliminary mechanistic studies are also presented. Copyright © 2006 American Chemical Society.

引用

页码：5338 / 5339

页数：2

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