Molecular oxygen to regenerate PdII active species

被引：118

作者：

Muzart, Jacques ^{[1
]}

机构：

[1] Univ Reims, CNRS, Unite Mixte Rech React Select & Applicat, F-51687 Reims 2, France

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2006年 / 1卷 / 04期

关键词：

homogeneous catalysis; oxidation; oxygen; palladium; regeneration;

D O I：

10.1002/asia.200600202

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium(II) catalysis allows various aerobic oxidation reactions, but the mechanism of the regeneration of the active catalytic species remains, in many cases, undetermined. In recent years, considerable effort has been directed toward the comprehension of the reaction of dioxygen with hydridopalladium(II) and palladium(0) complexes. This Focus Review highlights the results of these experimental and theoretical studies that can contribute to the exploitation of the powerful nature of Pd-II catalysis.

引用

页码：508 / 515

页数：8

共 76 条

[1] Mechanism of the palladium-catalyzed homocoupling of arylboronic acids: Key involvement of a palladium peroxo complex [J].

Adamo, Carlo ;

Amatore, Christian ;

Ciofini, Ilaria ;

Jutand, Anny ;

Lakmini, Hakim .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (21) :6829-6836

[2] Systematic synthesis of a series of hydroperoxo-, alkylperoxo- and μ-peroxo-palladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (TpiPr), TpiPrPd(py)-OOX [X = PdTpiPr(py), H, But], via dehydrative condensation of a hydroxo complex, TpiPrPd(py)-OH [J].

Akita, M ;

Miyaji, T ;

Hikichi, S ;

Moro-oka, Y .

CHEMICAL COMMUNICATIONS, 1998, (09) :1005-1006

[3]

[Anonymous], ANGEW CHEM

[4]

[Anonymous], ANGEW CHEM, DOI DOI 10.1002/ANGE.200602138

[5] Palladium-neocuproine catalyzed aerobic oxidation of alcohols in aqueous solvents [J].

Arends, IWCE ;

ten Brink, GJ ;

Sheldon, RA .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 251 (1-2) :246-254

[6] Mild aerobic oxidative palladium (II) catalyzed C-H bond functionalization: Regioselective and switchable C-H alkenylation and annulation of pyrroles [J].

Beck, EM ;

Grimster, NP ;

Hatley, R ;

Gaunt, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (08) :2528-2529

[7] Aerobic oxidative amination of unactivated alkenes catalyzed by palladium [J].

Brice, JL ;

Harang, JE ;

Timokhin, VI ;

Anastasi, NR ;

Stahl, SS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (09) :2868-2869

[8] Insertion of molecular oxygen into a palladium(II) hydride bond [J].

Denney, MC ;

Smythe, NA ;

Cetto, KL ;

Kemp, RA ;

Goldberg, KI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (08) :2508-2509

[9] The palladiuim-catalyzed oxidative kinetic resolution of secondary alcohols with molecular oxygen [J].

Ferreira, EM ;

Stoltz, BM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (31) :7725-7726

[10] Mechanistic questions about the reaction of molecular oxygen with palladium in oxidase catalysis [J].

Gligorich, Keith M. ;

Sigman, Matthew S. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (40) :6612-6615

← 1 2 3 4 5 6 7 8 →