Influence of physical state and molecular mobility of freeze-dried maltodextrin matrices on the oxidation rate of encapsulated lipids

被引:30
作者
Grattard, N [1 ]
Salaün, F [1 ]
Champion, D [1 ]
Roudaut, G [1 ]
Le Meste, M [1 ]
机构
[1] ENSBANA, Lab Ingn Mol & Sensorielle Aliment, F-21000 Dijon, France
关键词
encapsulation; lipids oxidation; freeze-drying; molecular mobility; second moment;
D O I
10.1111/j.1365-2621.2002.tb08851.x
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
A glassy model of freeze-dried maltodextrin was developed for the encapsulation of flaxseed oil. Kinetics of lipid oxidation have shown that the matrices efficiently protected lipids from oxidation for a moisture content corresponding to the monolayer value. An NMR method based on the 2nd moment, M(2) was used to study the molecular mobility and physical state of the freeze-dried maltodextrin and water mixtures. Physical state transitions were observed at temperatures very close to the glass transition temperature (Tg) determined from the equation of Vuataz (1999), suggesting a relationship between glass transition and proton relaxation behavior. No apparent relation between molecular mobility and oxidation rate were observed whatever the DE of maltodextrins.
引用
收藏
页码:3002 / 3010
页数:9
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