The controlled growth of oriented metal-organic frameworks on functionalized surfaces as followed by scanning force microscopy

被引：126

作者：

Munuera, Carmen ^{[1
]}

Shekhah, Osama ^{[2
]}

Wang, Hui ^{[2
]}

Woell, Christof ^{[2
]}

Ocal, Carmen ^{[1
]}

机构：

[1] Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain

[2] Ruhr Univ Bochum, Lehrstuhl Phys Chem 1, D-44780 Bochum, Germany

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2008年 / 10卷 / 48期

关键词：

D O I：

10.1039/b811010g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metal-organic frameworks (MOFs) selectively grown on COOH-functionalized surfaces have been investigated by scanning force microscopy. Thickness and surface roughness analysis reveals that the use of a novel protocol based on a layer-by-layer approach results in a controlled growth yielding extremely homogeneous and preferentially oriented materials. The results are described within a sequential growth model and turn out to be promising for building up MOF-based 3D architectures of high quality.

引用

页码：7257 / 7261

页数：5

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