Palladium-catalysed borylsilylation and borylstannylative dimerization of 1,2-dienes

被引：81

作者：

Onozawa, S ^{[1
]}

Hatanaka, Y ^{[1
]}

Tanaka, M ^{[1
]}

机构：

[1] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a905127i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A borylsilane regioselectively adds to 1,2-dienes in the presence of palladium complexes to afford high yields of alkenylboranes having allylsilane moieties, whereas a borylstannane gives a 1 : 2 telomer with 3-methylbuta-1,2-diene due to borylstannylative dimerization.

引用

页码：1863 / 1864

页数：2

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