Highly enantioselective aerobic oxidation of α-hydroxyphosphonates catalyzed by chiral vanadyl(V) methoxides bearing N-salicylidene-α-aminocarboxylates

被引：102

作者：

Pawar, Vijay D. ^{[1
]}

Bettigeri, Sampada ^{[1
]}

Weng, Shiue-Shien ^{[1
]}

Kao, Jun-Qi ^{[1
]}

Chen, Chien-Tien ^{[1
]}

机构：

[1] Natl Taiwan Normal Univ, Dept Chem, Taipei, Taiwan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 19期

关键词：

D O I：

10.1021/ja060639o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unprecedented vanadyl(V) methoxide complex 4 derived from 3,5-dibromo-N-salicylidene-l-tert-leucinate enables highly enantioselective aerobic oxidations of α-hydroxyphosphonates at ambient temperature with selectivity factors ranging from 3 to >99. Copyright © 2006 American Chemical Society.

引用

页码：6308 / 6309

页数：2

共 26 条

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