Surface-Bound Gradients for Studies of Soft Materials Behavior

被引:81
作者
Genzer, Jan [1 ]
机构
[1] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA
来源
ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 42 | 2012年 / 42卷
基金
美国国家科学基金会;
关键词
self-assembly; grafted polymer; polymer brush; screening; directed motion; combinatorial materials science; high throughput; soft materials; SELF-ASSEMBLED MONOLAYERS; HIGH-THROUGHPUT CHARACTERIZATION; TRANSFER RADICAL POLYMERIZATION; NANOPARTICLE-DENSITY GRADIENTS; DIRECTED CELL-MIGRATION; CHEMICAL GRADIENTS; WETTABILITY GRADIENT; COMBINATORIAL APPROACH; PROTEIN GRADIENTS; THIN-FILMS;
D O I
10.1146/annurev-matsci-070511-155050
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We provide a succinct account of surface-bound gradient structures created from soft materials or those facilitating the study of soft materials behavior. We commence by classifying the chief attributes of gradient structures and offer a few examples of fabrication methods employed to generate such structures. We then illustrate the versatility of gradient assemblies in functioning as recording media for monitoring a physico-chemical process, facilitating fast screening of physico-chemical phenomena, and playing an important part in the design and fabrication of surface-anchored molecular and macromolecular engines for the directed transport of soft materials.
引用
收藏
页码:435 / 468
页数:34
相关论文
共 231 条
[81]   Vascular Smooth Muscle Cell Durotaxis Depends on Substrate Stiffness Gradient Strength [J].
Isenberg, Brett C. ;
DiMilla, Paul A. ;
Walker, Matthew ;
Kim, Sooyoung ;
Wong, Joyce Y. .
BIOPHYSICAL JOURNAL, 2009, 97 (05) :1313-1322
[82]   Scanning electrochemical mapping of spatially localized electrochemical reactions induced by surface potential gradients [J].
Jayaraman, Shrisudersan ;
May, Erin L. ;
Hillier, Andrew C. .
LANGMUIR, 2006, 22 (25) :10322-10328
[83]   Generation of solution and surface gradients using microfluidic systems [J].
Jeon, NL ;
Dertinger, SKW ;
Chiu, DT ;
Choi, IS ;
Stroock, AD ;
Whitesides, GM .
LANGMUIR, 2000, 16 (22) :8311-8316
[84]   Effect of solvent quality and chain confinement on the kinetics of polystyrene bromination [J].
Jhon, Young K. ;
Semler, James J. ;
Genzer, Jan .
MACROMOLECULES, 2008, 41 (18) :6719-6727
[85]   Effect of Comonomer Sequence Distribution on the Adsorption of Random Copolymers onto Impenetrable Flat Surfaces [J].
Jhon, Young K. ;
Semler, James J. ;
Genzer, Jan ;
Beevers, Martin ;
Gus'kova, Olga A. ;
Khalatur, Pavel G. ;
Khokhlov, Alexei R. .
MACROMOLECULES, 2009, 42 (07) :2843-2853
[86]   Synthesis of Polymer Thin Film Gradient with Nanometer Thickness through Water Diffusion Controlled Surface Polymerization [J].
Jiang, Dawei ;
Huang, Xueying ;
Qiu, Fei ;
Luo, Chuping ;
Huang, Lequn Lee .
MACROMOLECULES, 2010, 43 (01) :71-76
[87]   Gradient chemical micropatterns: A reference substrate for surface nanometrology [J].
Julthongpiput, D ;
Fasolka, MJ ;
Zhang, WH ;
Nguyen, T ;
Amis, EJ .
NANO LETTERS, 2005, 5 (08) :1535-1540
[88]   Changing directions in the study of chemotaxis [J].
Kay, Robert R. ;
Langridge, Paul ;
Traynor, David ;
Hoeller, Oliver .
NATURE REVIEWS MOLECULAR CELL BIOLOGY, 2008, 9 (06) :455-463
[89]   Biomolecular gradients in cell culture systems [J].
Keenan, Thomas M. ;
Folch, Albert .
LAB ON A CHIP, 2008, 8 (01) :34-57
[90]   Combinatorial screen of the effect of surface energy on fibronectin-mediated osteoblast adhesion, spreading and proliferation [J].
Kennedy, SB ;
Washburn, NR ;
Simon, CG ;
Amis, EJ .
BIOMATERIALS, 2006, 27 (20) :3817-3824