Low-temperature synthesis of star-shaped PbS nanocrystals in aqueous solutions of mixed cationic/anionic surfactants

被引:258
作者
Zhao, N [1 ]
Qi, LM [1 ]
机构
[1] Peking Univ, Coll Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China
关键词
D O I
10.1002/adma.200501756
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Uniform, well-defined star-shaped PbS nanocrystals with tunable sizes (40-100 nm, see Figure), as well as octahedral PbS nanocrystals, have been readily synthesized in aqueous solutions containing a mixture of the surfactants cetyltrimethylammonium bromide/sodium dodecyl sulfate (CTAB/SDS) at low temperature (80 degrees C). The size of the PbS nanostars can be accurately controlled by adjusting the reaction time. This result may open new avenues for the green chemical synthesis of shape-controlled semiconductor nanocrystals.
引用
收藏
页码:359 / +
页数:5
相关论文
共 39 条
[11]   Generalized and facile synthesis of semiconducting metal sulfide nanocrystals [J].
Joo, J ;
Na, HB ;
Yu, T ;
Yu, JH ;
Kim, YW ;
Wu, FX ;
Zhang, JZ ;
Hyeon, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (36) :11100-11105
[12]   Architectural control of magnetic semiconductor nanocrystals [J].
Jun, YW ;
Jung, YY ;
Cheon, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (04) :615-619
[13]   Symmetry-controlled colloidal nanocrystals: Nonhydrolytic chemical synthesis and shape determining parameters [J].
Jun, YW ;
Lee, JH ;
Choi, JS ;
Cheon, J .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (31) :14795-14806
[14]   Controlled synthesis of multi-armed CdS nanorod architectures using monosurfactant system [J].
Jun, YW ;
Lee, SM ;
Kang, NJ ;
Cheon, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (21) :5150-5151
[15]   Surfactant-assisted growth of novel PbS dendritic nanostructures via facile hydrothermal process [J].
Kuang, DB ;
Xu, AW ;
Fang, YP ;
Liu, HQ ;
Frommen, C ;
Fenske, D .
ADVANCED MATERIALS, 2003, 15 (20) :1747-+
[16]   Single-crystalline star-shaped nanocrystals and their evolution: Programming the geometry of nano-building blocks [J].
Lee, SM ;
Jun, YW ;
Cho, SN ;
Cheon, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (38) :11244-11245
[17]   Anisotropic shape control of colloidal inorganic nanocrystals [J].
Lee, SM ;
Cho, SN ;
Cheon, J .
ADVANCED MATERIALS, 2003, 15 (05) :441-444
[18]   Efficient infrared-emitting PbS quantum dots grown on DNA and stable in aqueous solution and blood plasma [J].
Levina, L ;
Sukhovatkin, W ;
Musikhin, S ;
Cauchi, S ;
Nisman, R ;
Bazett-Jones, DP ;
Sargent, EH .
ADVANCED MATERIALS, 2005, 17 (15) :1854-+
[19]   Preparation of Ag2S nanocrystals of predictable shape and size [J].
Lim, WP ;
Zhang, Z ;
Low, HY ;
Chin, WS .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (42) :5685-5689
[20]   Shape evolution and self assembly of monodisperse PbTe nanocrystals [J].
Lu, WG ;
Fang, JY ;
Stokes, KL ;
Lin, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (38) :11798-11799