Practical palladium catalysts for C-N and C-O bond formation

被引：1218

作者：

Muci, AR ^{[1
]}

Buchwald, SL ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

CROSS-COUPLING REACTIONS: A PRACTICAL GUIDE | 2002年 / 219卷

关键词：

amination; arylation; catalyst; ligand; palladium;

D O I：

10.1007/3-540-45313-X_5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of new palladium catalysts for the arylation of amines and alcohols with aryl halides and sulfonates is reviewed. Initial systems as well as mechanistic issues are discussed briefly, while subsequent generations of catalysts are described in greater detail. For these later generations of catalysts, substrate scope and limitations are also discussed. The review is organized by substrate class. Modifications and improvements in technical aspects of reaction development are described where appropriate. In addition, applications of this technology toward natural product synthesis, new synthetic methodology, and medicinal chemistry are chronicled. This review is organized in a manner that is designed to be useful to the synthetic organic chemist.

引用

页码：131 / 209

页数：79

共 198 条

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