Double C-H activation in a Rh-NHC complex leading to the isolation of a 14-electron Rh(III) complex

被引：111

作者：

Dorta, R ^{[1
]}

Stevens, ED ^{[1
]}

Nolan, SP ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 16期

关键词：

D O I：

10.1021/ja049545+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvent-dependent interaction of ItBu with a Rh(I)-olefin complex leads to the isolation of two precursors en route to a unique double cyclometalation process. Abstraction of the chloride ligand from the resulting complex enables the isolation of a bare" 14-electron Rh(III) complex. Copyright © 2003 American Chemical Society."

引用

页码：5054 / 5055

页数：2

共 33 条

[1] FACILE REVERSIBLE METALATION IN AN AGOSTIC COMPLEX AND HYDROGENOLYSIS OF A METAL ARYL COMPLEX VIA A DIHYDROGEN COMPLEX
ALBENIZ, AC
SCHULTE, G
CRABTREE, RH
[J]. ORGANOMETALLICS, 1992, 11 (01) : 242 - 249
[2] A STABLE CRYSTALLINE CARBENE
ARDUENGO, AJ
HARLOW, RL
KLINE, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
[3] Novel T-shaped 14-electron platinum(II) complexes stabilized by one agostic interaction
Baratta, W
Stoccoro, S
Doppiu, A
Herdtweck, E
Zucca, A
Rigo, P
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (01) : 105 - 108
[4] Baratta W, 1999, ANGEW CHEM INT EDIT, V38, P1629, DOI 10.1002/(SICI)1521-3773(19990601)38:11<1629::AID-ANIE1629>3.0.CO
[5] 2-L
[6] Stable carbenes
Bourissou, D
Guerret, O
Gabbaï, FP
Bertrand, G
[J]. CHEMICAL REVIEWS, 2000, 100 (01) : 39 - 91
[7] BROOKHART M, 1988, PROG INORG CHEM, V36, P1
[8] A stable three-coordinate rhodium(I) olefin complex
Budzelaar, PHM
de Gelder, R
Gal, AW
[J]. ORGANOMETALLICS, 1998, 17 (19) : 4121 - 4123
[9] An unprecedented dinuclear alkylrhodium(III) complex built up by two 14-electron [RhCl2(alkyl)(PR3)] units
Canepa, G
Brandt, CD
Werner, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (33) : 9666 - 9667
[10] Collman J.P., 1987, PRINCIPLES APPL ORGA

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