Silver(I) coordination polymer of 2,5-bis(4′,5′-bis(methylthio)-1′,3′-dithiol-2′-ylidene)-1,3,4,6-tetrathiapentalene (TTM-TTP) and its highly conductive iodine derivative

被引：45

作者：

Zhong, JC

Misaki, Y

Munakata, M

Kuroda-Sowa, T

Maekawa, M

Suenaga, Y

Konaka, H

机构：

[1] Kinki Univ, Dept Chem, Higashiosaka, Osaka 5778502, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Kyoto 6068501, Japan

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 27期

关键词：

D O I：

10.1021/ic010630h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel silver(I) coordination polymer with 2,5-bis(4',5'-bis(methylthio)-1',3'-dithiol-2'ylidene)-1,3,4,6-tetrathiapentalene (TTM-TTP), [Ag(TTM-TTP)(CF3SO3)](n) (1), which consists of 1-D waving chains, was synthesized and characterized. Polymer 1 can be also regarded as a 3-D supramolecular network formed via many shorter side-by-side and face-to-face (SS)-S-... contacts. This polymer and its iodine-doped compound 2 behave as semiconductors with σ(25°C) values of 7.1 x 10(-6) and 0.85 S cm(-1), respectively. [GRAPHICS]

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页码：7096 / +

页数：4

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