Potentialities and draw-backs of the experimental approach to the study of high T and high GHSV kinetics

被引：21

作者：

Beretta, A ^{[1
]}

Groppi, G ^{[1
]}

Majocchi, L ^{[1
]}

Forzatti, P ^{[1
]}

机构：

[1] Politecn Milan, Dipartimento Chim Ind & Ingn Chim, I-20133 Milan, Italy

来源：

APPLIED CATALYSIS A-GENERAL | 1999年 / 187卷 / 01期

关键词：

kinetics of ultra-fast processes; catalytic partial oxidation; catalytic combustion; syngas production; olefin production; annular reactor; homogeneous-heterogeneous reactions;

D O I：

10.1016/S0926-860X(99)00182-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Open space for improvements of the kinetic investigation for fast reactions at high temperature (high T) and extremely short contact times is offered by the development of more adequate experimental tools. Kinetic data of catalytic CO combustion, partial oxidation of methane and oxidative dehydrogenation of propane, which had been obtained under controlled operating conditions and under the estimated influence of mass-transfer and homogeneous reactions, were fundamental for the correct interpretation of the more complex performance of an adiabatic structured reactor. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：49 / 60

页数：12

共 30 条

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