Facile Postpolymerization End-Modification of RAFT Polymers

被引：78

作者：

Spruell, Jason M. ^{[1
]}

Levy, Benjamin A. ^{[2
]}

Sutherland, Alexander ^{[2
]}

Dichtel, William R. ^{[1
]}

Cheng, Joy Y. ^{[2
]}

Stoddart, J. Fraser ^{[1
]}

Nelson, Alshakim ^{[2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] IBM Corp, Almaden Res Ctr, San Jose, CA 95120 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2009年 / 47卷 / 02期

基金：

美国国家科学基金会;

关键词：

block copolymer; phase separation; postpolymerization modification; reduction/conjugation; reversible addition fragmentation chain transfer (RAFT); CHAIN-TRANSFER POLYMERIZATION; LIVING RADICAL POLYMERIZATION; FUNCTIONALIZED BLOCK-COPOLYMERS; CLICK CHEMISTRY; DIBLOCK COPOLYMERS; THIN-FILMS; SURFACE-CHEMISTRY; NANOPARTICLES; POLYSTYRENE; EFFICIENT;

D O I：

10.1002/pola.23138

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

One-pot methods for the end-group postpolymerization modification of reversible addition fragmentation chain transfer (RAFT) derived polymers were investigated. Dithioester-terminated polymers were transformed into omega-functionalized polymers through conjugate addition of a variety of acrylates with an intermediate thiol. These methods provide a versatile means of introducing a variety of functionalities onto the polymer terminus, while simultaneously removing the residual dithiobenzoate group. A series of functionalized polymetbylmethaerylate-b-polystyrene (PMMA-b-PS) polymers were synthesized utilizing the developed methods to probe the effect of charged end groups on diblock copolymer phase separation in thin films. (C) 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 346-356, 2009

引用

页码：346 / 356

页数：11

共 57 条

[1] The future of reversible addition fragmentation chain transfer polymerization [J].

Barner-Kowollik, Christopher ;

Perrier, Sebastien .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (17) :5715-5723

[2] Stability and Utility of Pyridyl Disulfide Functionality in RAFT and Conventional Radical Polymerizations [J].

Boyer, Cyrille ;

Liu, Jingquan ;

Wong, Lingjiun ;

Tippett, Michael ;

Bulmus, Volga ;

Davis, Thomas P. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (21) :7207-7224

[3] Controlled/living radical polymerization: Features, developments, and perspectives [J].

Braunecker, Wade A. ;

Matyjaszewski, Krzysztof .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (01) :93-146

[4] Convergent synthesis of 3-arm star polymers from RAFT-prepared poly(N,N-diethylacrylamide) via a thiol-ene click reaction [J].

Chan, Justin W. ;

Yu, Bing ;

Hoyle, Charles E. ;

Lowe, Andrew B. .

CHEMICAL COMMUNICATIONS, 2008, (40) :4959-4961

[5] Mechanisms of excimer formation in poly(acenaphthylene) [J].

Chen, M ;

Ghiggino, KP ;

Smith, TA ;

Thang, SH ;

Wilson, GJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2004, 57 (12) :1175-1177

[6] Dense self-assembly on sparse chemical patterns: Rectifying and multiplying lithographic patterns using block copolymers [J].

Cheng, Joy Y. ;

Rettner, Charles T. ;

Sanders, Daniel P. ;

Kim, Ho-Cheol ;

Hinsberg, William D. .

ADVANCED MATERIALS, 2008, 20 (16) :3155-3158

[7] Nanostructure engineering by templated self-assembly of block copolymers [J].

Cheng, JY ;

Mayes, AM ;

Ross, CA .

NATURE MATERIALS, 2004, 3 (11) :823-828

[8] Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].

Chiefari, J ;

Chong, YK ;

Ercole, F ;

Krstina, J ;

Jeffery, J ;

Le, TPT ;

Mayadunne, RTA ;

Meijs, GF ;

Moad, CL ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1998, 31 (16) :5559-5562

[9] Thermolysis of RAFT-synthesized poly(methyl methacrylate) [J].

Chong, Bill ;

Moad, Graeme ;

Rizzardo, Ezio ;

Skidmore, Melissa ;

Thang, San H. .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2006, 59 (10) :755-762

[10] A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization: The RAFT process [J].

Chong, YK ;

Le, TPT ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1999, 32 (06) :2071-2074

← 1 2 3 4 5 6 →